Deprotection of Ketoximes Using Bismuth(III) Nitrate Pentahydrate

Ram S. Mohan; Bryce A. Nattier; Kyle J. Eash

Deprotection of Ketoximes Using Bismuth(III) Nitrate Pentahydrate

Ram S. Mohan, Bryce A. Nattier, Kyle J. Eash

Illinois Wesleyan University

Research output: Journal Article › Article › peer-review

Abstract

Ketoximes undergo facile deprotection in acetone-H20 (9: 1) in the presence 01' 0.5 equivalents of Bi(N03h•5H20. Bismuth(III) nitrate is relatively non-toxic, insensitive to air and inexpensive. These features coupled with the use of a relatively nontoxic solvent system make this method an attractive alternative to existing routes for deprotection of ketoximes.

Original language	American English
Journal	Synthesis
Volume	7
State	Published - 2001

Keywords

bismuth and compounds
deprotection
oximes
protecting

Disciplines

Organic Chemistry

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Cite this

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title = "Deprotection of Ketoximes Using Bismuth(III) Nitrate Pentahydrate",

abstract = " Ketoximes undergo facile deprotection in acetone-H20 (9: 1) in the presence 01' 0.5 equivalents of Bi(N03h•5H20. Bismuth(III) nitrate is relatively non-toxic, insensitive to air and inexpensive. These features coupled with the use of a relatively nontoxic solvent system make this method an attractive alternative to existing routes for deprotection of ketoximes.",

keywords = "bismuth and compounds, deprotection, oximes, protecting",

author = "Mohan, {Ram S.} and Nattier, {Bryce A.} and Eash, {Kyle J.}",

year = "2001",

language = "American English",

volume = "7",

journal = "Synthesis",

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TY - JOUR

T1 - Deprotection of Ketoximes Using Bismuth(III) Nitrate Pentahydrate

AU - Mohan, Ram S.

AU - Nattier, Bryce A.

AU - Eash, Kyle J.

PY - 2001

Y1 - 2001

N2 - Ketoximes undergo facile deprotection in acetone-H20 (9: 1) in the presence 01' 0.5 equivalents of Bi(N03h•5H20. Bismuth(III) nitrate is relatively non-toxic, insensitive to air and inexpensive. These features coupled with the use of a relatively nontoxic solvent system make this method an attractive alternative to existing routes for deprotection of ketoximes.

AB - Ketoximes undergo facile deprotection in acetone-H20 (9: 1) in the presence 01' 0.5 equivalents of Bi(N03h•5H20. Bismuth(III) nitrate is relatively non-toxic, insensitive to air and inexpensive. These features coupled with the use of a relatively nontoxic solvent system make this method an attractive alternative to existing routes for deprotection of ketoximes.

KW - bismuth and compounds

KW - deprotection

KW - oximes

KW - protecting

M3 - Article

VL - 7

JO - Synthesis

JF - Synthesis

ER -