Iron(III) Tosylate-Catalyzed Deprotection of Aromatic Acetals in Water

Ram S. Mohan; Margaret E. Olson; James P. Carolan; Michael V. Chiodo; Phillip R. Lazzara

Iron(III) Tosylate-Catalyzed Deprotection of Aromatic Acetals in Water

Ram S. Mohan, Margaret E. Olson, James P. Carolan, Michael V. Chiodo, Phillip R. Lazzara

Illinois Wesleyan University

Research output: Journal Article › Article › peer-review

Abstract

The deprotection of aromatic as well as conjugated acetals and ketals in water is catalyzed by iron(III) tosylate (1.0–5.0 mol %). Iron(III) tosylate is an inexpensive and readily available catalyst. The use of water, the most environmentally benign solvent, makes this procedure especially attractive for acetal deprotection.

Original language	American English
Journal	Tetrahedron Letters
Volume	51
State	Published - 2010

Disciplines

Organic Chemistry

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Cite this

@article{76feff05e51245e58aae0efc83119d9e,

title = "Iron(III) Tosylate-Catalyzed Deprotection of Aromatic Acetals in Water",

abstract = " The deprotection of aromatic as well as conjugated acetals and ketals in water is catalyzed by iron(III) tosylate (1.0–5.0 mol %). Iron(III) tosylate is an inexpensive and readily available catalyst. The use of water, the most environmentally benign solvent, makes this procedure especially attractive for acetal deprotection.",

author = "Mohan, {Ram S.} and Olson, {Margaret E.} and Carolan, {James P.} and Chiodo, {Michael V.} and Lazzara, {Phillip R.}",

year = "2010",

language = "American English",

volume = "51",

journal = "Tetrahedron Letters",

}

TY - JOUR

T1 - Iron(III) Tosylate-Catalyzed Deprotection of Aromatic Acetals in Water

AU - Mohan, Ram S.

AU - Olson, Margaret E.

AU - Carolan, James P.

AU - Chiodo, Michael V.

AU - Lazzara, Phillip R.

PY - 2010

Y1 - 2010

N2 - The deprotection of aromatic as well as conjugated acetals and ketals in water is catalyzed by iron(III) tosylate (1.0–5.0 mol %). Iron(III) tosylate is an inexpensive and readily available catalyst. The use of water, the most environmentally benign solvent, makes this procedure especially attractive for acetal deprotection.

AB - The deprotection of aromatic as well as conjugated acetals and ketals in water is catalyzed by iron(III) tosylate (1.0–5.0 mol %). Iron(III) tosylate is an inexpensive and readily available catalyst. The use of water, the most environmentally benign solvent, makes this procedure especially attractive for acetal deprotection.

M3 - Article

VL - 51

JO - Tetrahedron Letters

JF - Tetrahedron Letters

ER -